One of the key technologies in the development of nanotechnology has been scanning probe microscopy, and one of the key technologies that has made scanning probe microscopies possible is piezoelectric materials. Researchers have now integrated a single-crystal material with “giant” piezoelectric properties onto silicon. Improved actuators for nanopositioning devices are listed among the several possible applications of improved piezoelectric materials. Will these actuators be used to integrate scanning probe microscopes on a chip and would such instruments be useful for atomically precise manufacturing? ScienceDaily reprints the University of Wisconsin-Madison news release:

Integrating a complex, single-crystal material with “giant” piezoelectric properties onto silicon, University of Wisconsin-Madison engineers and physicists can fabricate low-voltage, near-nanoscale electromechanical devices that could lead to improvements in high-resolution 3-D imaging, signal processing, communications, energy harvesting, sensing, and actuators for nanopositioning devices, among others.

Led by Chang-Beom Eom, a UW-Madison professor of materials science and engineering and physics, the multi-institutional team published its results in the November 18 issue of the journal Science [abstract]. …

Eom studies the advanced piezoelectric material lead magnesium niobate-lead titanate, or PMN-PT. Such materials exhibit a “giant” piezoelectric response that can deliver much greater mechanical displacement with the same amount of electric field as traditional piezoelectric materials. They also can act as both actuators and sensors. For example, they use electricity to deliver an ultrasound wave that penetrates deeply into the body and returns data capable of displaying a high-quality 3-D image.

Currently, a major limitation of these advanced materials is that to incorporate them into very small-scale devices, researchers start with a bulk material and grind, cut and polish it to the size they desire. It’s an imprecise, error-prone process that’s intrinsically ill-suited for nanoelectromechanical systems (NEMS) or microelectromechanical systems (MEMS).

Until now, the complexity of PMN-PT has thwarted researchers’ efforts to develop simple, reproducable microscale fabrication techniques.

Applying microscale fabrication techniques such as those used in computer electronics, Eom’s team has overcome that barrier. He and his colleagues worked from the ground up to integrate PMN-PT seamlessly onto silicon. Because of potential chemical reactions among the components, they layered materials and carefully planned the locations of individual atoms.

“You have to lay down the right element first,” says Eom.

Onto a silicon “platform,” his team adds a very thin layer of strontium titanate, which acts as a template and mimics the structure of silicon. Next comes a layer of strontium ruthenate, an electrode Eom developed some years ago, and finally, the single-crystal piezoelectric material PMN-PT.

The researchers have characterized the material’s piezoelectric response, which correlates with theoretical predictions.

“The properties of the single crystal we integrated on silicon are as good as the bulk single crystal,” says Eom.

His team calls devices fabricated from this giant piezoelectric material “hyper-active MEMS” for their potential to offer researchers a high level of active control. Using the material, his team also developed a process for fabricating piezoelectric MEMS.

We will have to watch to see if the use of this material in fabricating piezoelectric MEMS leads to improvements in the use of scanning probes for atomically precise manufacturing.